Self-flux growth of large EuCu2Si2 single crystals

✍ Scribed by Chongde Cao; Wolfgang Löser; Günter Behr; Rüdiger Klingeler; Norman Leps; Hartmut Vinzelberg; Bernd Büchner

• Book ID: 104022158
• Publisher: Elsevier Science
• Year: 2011
• Tongue: English
• Weight: 672 KB
• Volume: 318
• Category: Article
• ISSN: 0022-0248
• DOI: 10.1016/j.jcrysgro.2010.10.197

✦ Synopsis

Large single crystals of the EuCu 2 Si 2 intermetallic compound have been successfully grown by a high pressure vertical floating zone method with optical heating. The suppression of evaporation of volatile elements and control of the floating zone temperature are the key factors for the stability of the growth process. A low travelling velocity of 3 mm/h and a short length of the floating zone play an important role in phase selection and formation of a EuCu 2 Si 2 single crystal. Measurements of oriented single crystalline EuCu 2 Si 2 samples reveal a non-linear temperature dependence of the magnetic susceptibility attributed to the valence fluctuations in Eu ion. But no magnetic ordering transition occurs at T42 K. The magnetic susceptibility data display significant anisotropy with a magnetic easy c-axis ([0 0 1]). In contrast to the magnetic susceptibility, the anisotropy in the electrical resistivity for the two different crystallographic orientations is less significant.