## Abstract A flash photolysis setup coupled to UV absorption spectrometry detection was used to measure the UV absorption spectra of the (CH~3~)~2~(CH~2~O~2~.)CC(O)C(CH~3~)~3~ and (CH~3~)~2~(CH~2~O~2~.)CC(O)CH~3~ radicals between 207 and 290 nm. The selfโreaction rate constants of these radicals w
Self-exchange rate constants for acidic and basic plastocyanins from cross reaction studies
โ Scribed by P Kyritsis; K Govindaraju; C.A. Dennison; A.G. Sykes
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 86 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0162-0134
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In previous paperslp4 we described the formation and the identification in non--polar solvents of mixed ligand complexes some dithiocarbamate (DTC) complexes with different N-alkyl substituents according to the equation: 2 A similar exchange reaction was studied by other authors and the mixed ligan
The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f