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Self-diffusion of small molecules in cellulose gels using FT-pulsed field gradient NMR

✍ Scribed by Wyn Brown; Peter Stilbs; Tom Lindström


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
298 KB
Volume
29
Category
Article
ISSN
0021-8995

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✦ Synopsis


Transport in cellulose gels has been studied with ethylene glycol and crown ether (15-5) as "probes" using an NMR spin-echo technique. The cellulose content was varied in range 20-5570 (w/w). The retardation of diffusion was found to be adequately described by simple first-order expressions in concentration of cellulose.


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✍ R. Knauss; J. Schiller; G. Fleischer; J. Kärger; K. Arnold 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

Pulsed field gradient (PFG) nuclear magnetic resonance (NMR) was used to investigate the self-diffusion behavior of water molecules in cartilage, polymeric cartilage components, and different model polymers. The short-time self-diffusion coefficients (diffusion time ⌬ D 13 msec) are found to decreas