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Self-Diffusion of Ions in Nafion-117 Membrane Having Mixed Ionic Composition

✍ Scribed by Chaudhury, Sanhita; Agarwal, Chhavi; Pandey, A. K.; Goswami, A.


Book ID
120544955
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
699 KB
Volume
116
Category
Article
ISSN
0022-3654

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The tritium tagged water (HTO) exchange rates between water swollen Nafion-117 membrane and equilibrating water were measured to obtain self-diffusion coefficients of water (D m H 2 O ) in the membrane samples with several multivalent counterions, viz. Ba 2+ , Fe 3+ , Y 3+ , La 3+ , Eu 3+ and Th 4+

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The self-diffusion coefficient of water in Nafion-117 membrane in different cationic forms was measured by the transient radiotracer method, which is based on an analytical solution of Fick's second law. The self-diffusion coefficient of water in the membrane was obtained from the analysis of time-d