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Self diffusion in iron

✍ Scribed by F.S Buffington; K Hirano; M Cohen


Publisher
Elsevier Science
Year
1961
Weight
528 KB
Volume
9
Category
Article
ISSN
0001-6160

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✦ Synopsis


Self-diffusion in high-purity iron (99.97 per cent Fe) has been determined over the temperature r8nge from 700 to 1438Β°C. The temperature dependence of the self-diffusion coefficient in fete-centered cubic and in body-centered cubic iron can be expressed as follows (in cm*/sec):

Gamma

-iron: D = 0.18 exp (-64,5OO/RT) Alpha-iron (paramagnetic): D = 1.9 exp (-67,2OO/RT) (above 790Β° C) Alpha-iron (ferromagnetic): D = 2.0 exp ( -6O,OOO/RT) (below 750' C). The diffusivity below the magnetic treneformation is lower than expected from an extrapolation of the diffusion data for paramagnetic alpha-iron. AUTO-DIFFUSION DU FER Les auteurs ont Btudie I'autodiffusion du fer pur (99,97% Fe) dans un domaine de t.emp&ature variant de 700' a 1436'C. L'influence de la temp&ature sur le coefficient d'auto-diffusion du fer cubique a feces cent&s et du fer cubique cent& peut Btre exprimee comme suit (en cm*/sec): Fer gamma: D = 0.18 exp (-64 SOO/RT) Fer alpha (peramagnetique): D = 1,9 exp (-57 2OO/RT) (au-dessus de 790Β°C) Fer alpha (ferromagnetique): I1 = 2,0 exp (-60 OOO/RT) (en-dessous de 750Β°C) La veleur du coefficient de diffusion en-dessous du point de transformation magnetique est plue faible que la valeur obtenue par extrapolation 8 partir des donneos du fer alpha peramagn&ique. SELBSTDIFFUSION IN EISEN Die Selbstdiffusion in sehr reinem Eisen (99,97% Fe) wurde im Temperaturbereich 700" bis 1436Β°C bestimmt. Die TemperaturabhBngigkeit des Selbstdiffusionakoeffisienten in kubisch-Alichensentriertem und kubisch-raumsentriertem Eisen l&LX sich folgendcrmal3en ausdliicken (in cm*/sec): Gamma-Ei.sen: D = 0.18 cxp (-64 500/RT) Alpha-Eisen (p8r8m8gnetisCh): D = I,9 exp (-57 2OO/RT) (oberhelb 790Β°C) Alpha-Eisen (forromagnotisch): D = 2.0 oxp (-60 OOO/RT) (unterhalb 750Β°C). Die Diffusionskonstante unterhalb der magnatischen Umwandlung ist niedriger, als man nach Extrapolation der Diffusionsmessungon fur paramagnetisches Eisen crwartet. * This research is part of 8 program sponsored by the Engineering Foundat ion, the Wright Air Development Center under Contract AF 33 (816)-3264, and U.S. Atomic Energy Commission under Contract AT (30-l)-1975.


πŸ“œ SIMILAR VOLUMES


Note on the self-diffusion in iron
✍ W. Hume-Rothery πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science βš– 125 KB

Surface dissolution is thus expected to be faster in such localities. The probability of occurrence of dissolution figures on cold-worked samples is therefore likely to increase partly because of the increased number of dislocation sites on the surface, and partly because of the annealing out of the