Surface dissolution is thus expected to be faster in such localities. The probability of occurrence of dissolution figures on cold-worked samples is therefore likely to increase partly because of the increased number of dislocation sites on the surface, and partly because of the annealing out of the
Self diffusion in iron
β Scribed by F.S Buffington; K Hirano; M Cohen
- Publisher
- Elsevier Science
- Year
- 1961
- Weight
- 528 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0001-6160
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β¦ Synopsis
Self-diffusion in high-purity iron (99.97 per cent Fe) has been determined over the temperature r8nge from 700 to 1438Β°C. The temperature dependence of the self-diffusion coefficient in fete-centered cubic and in body-centered cubic iron can be expressed as follows (in cm*/sec):
Gamma
-iron: D = 0.18 exp (-64,5OO/RT) Alpha-iron (paramagnetic): D = 1.9 exp (-67,2OO/RT) (above 790Β° C) Alpha-iron (ferromagnetic): D = 2.0 exp ( -6O,OOO/RT) (below 750' C). The diffusivity below the magnetic treneformation is lower than expected from an extrapolation of the diffusion data for paramagnetic alpha-iron. AUTO-DIFFUSION DU FER Les auteurs ont Btudie I'autodiffusion du fer pur (99,97% Fe) dans un domaine de t.emp&ature variant de 700' a 1436'C. L'influence de la temp&ature sur le coefficient d'auto-diffusion du fer cubique a feces cent&s et du fer cubique cent& peut Btre exprimee comme suit (en cm*/sec): Fer gamma: D = 0.18 exp (-64 SOO/RT) Fer alpha (peramagnetique): D = 1,9 exp (-57 2OO/RT) (au-dessus de 790Β°C) Fer alpha (ferromagnetique): I1 = 2,0 exp (-60 OOO/RT) (en-dessous de 750Β°C) La veleur du coefficient de diffusion en-dessous du point de transformation magnetique est plue faible que la valeur obtenue par extrapolation 8 partir des donneos du fer alpha peramagn&ique. SELBSTDIFFUSION IN EISEN Die Selbstdiffusion in sehr reinem Eisen (99,97% Fe) wurde im Temperaturbereich 700" bis 1436Β°C bestimmt. Die TemperaturabhBngigkeit des Selbstdiffusionakoeffisienten in kubisch-Alichensentriertem und kubisch-raumsentriertem Eisen l&LX sich folgendcrmal3en ausdliicken (in cm*/sec): Gamma-Ei.sen: D = 0.18 cxp (-64 500/RT) Alpha-Eisen (p8r8m8gnetisCh): D = I,9 exp (-57 2OO/RT) (oberhelb 790Β°C) Alpha-Eisen (forromagnotisch): D = 2.0 oxp (-60 OOO/RT) (unterhalb 750Β°C). Die Diffusionskonstante unterhalb der magnatischen Umwandlung ist niedriger, als man nach Extrapolation der Diffusionsmessungon fur paramagnetisches Eisen crwartet. * This research is part of 8 program sponsored by the Engineering Foundat ion, the Wright Air Development Center under Contract AF 33 (816)-3264, and U.S. Atomic Energy Commission under Contract AT (30-l)-1975.
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