Self-diffusion and sedimentation of dextran in concentrated solutions
β Scribed by Brown, W. ;Stilbs, P. ;Johnsen, R. M.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1982
- Tongue
- English
- Weight
- 386 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0098-1273
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β¦ Synopsis
Abstract
Frictional coefficients for dextran in water have been evaluated from (i) selfβdiffusion coefficients determined by pulsedβfieldβgradient NMR, and (ii) sedimentation coefficients in concentrated solutions. The results show that these frictional coefficients are only equal at infinite dilution and that f~s~ increases more rapidly than f~D~^*^ as the concentration increases.
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The polymers amylose, cellulose, and dextran are compared with regard to their conformation. The comparison is based on a combination of sedimentation and electron-spin resonance or fluorecence-depolarization data according to a theory developed for the sedimentation of polymer coils. The comparison
The scdimeiit;ttioii cocflicieiit of c d f thyiiius a i d of T i I)NA w:is dctcriiiiiictl :il sc:vc~~il c,oiic:eiitratioiis tip to saturation i i i solrit.ioiis of each of the following d t s : JIgCL, AIgBr?, and RIgSSO4. Under certaiii coiiditioris, :t plot of the prodrict of the i ~h t ive viscosi