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Self-diffusion and nuclear spin-lattice relaxation time in aqueous solutions of sodium carboxymethylcellulose

✍ Scribed by A. I. Toryanik; V. G. Pogrebnyak; V. V. Kisel'nik; N. G. Malyuk

Book ID
112362919
Publisher
Springer
Year
1974
Tongue
English
Weight
78 KB
Volume
10
Category
Article
ISSN
0040-5760

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The 29Si spin-lattice relaxation times, &(%), of the various silicate anions present in high-purity alkaline silicate solutions are reported. Regular silicate cages display the longest T,(29Si) values and, in the case of the cubic octamenc cage, an unexpectedly large nuclear Overhauser enhancement,