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Self-Assembly of Three CdII- and CuII-Containing Coordination Polymers from 4,4′-Dipyridyl Disulfide

✍ Scribed by Junhua Luo; Maochun Hong; Ruihu Wang; Daqiang Yuan; Rong Cao; Lei Han; Yanqing Xu; Zhengzhong Lin

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 271 KB
Volume: 2003
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200300153

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip