Self-Assembly of Organodiphosphonate, Polyoxomolybdate and Diphenanthrolinecobalt(II) into Two Clusters and One Linear Polymer

✍ Scribed by Rui-Biao Fu; Xin-Tao Wu; Sheng-Min Hu; Jian-Jun Zhang; Zhi-Yong Fu; Wen-Xin Du; Sheng-Qing Xia

• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 126 KB
• Volume: 2003
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/ejic.200200678

✦ Synopsis

Abstract

[{Co(1,10‐phen)~2~}~2~{(Mo~4~O~12~)(O~3~PCH~2~CH~2~PO~3~)}·(H~2~O)] (1), [{Co(1,10‐phen)~2~}~2~{(Mo~4~O~12~)(O~3~PCH~2~CH~2~CH~2~PO~3~)}·(1.5H~2~O)] (2) and [{Co(1,10‐phen)~2~(H~2~O)~2~}{Co(1,10‐phen)~2~(H~2~O)}{(Mo~5~O~15~)(O~3~PCH~2~CH~2~CH~2~CH~2~PO~3~)}·(6H~2~O)] (3) were synthesized by self‐assembly of H~2~O~3~P(CH~2~)~n~PO~3~H~2~ (n = 2−4), polyoxomolybdate and [Co(1,10‐phen)~2~]^2+^ (1,10‐phen = 1,10‐phenanthroline) under hydrothermal conditions. Compounds 1 and 2 are novel heterometallic hexanuclear clusters, while compound 3 is a new linear polymer. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)