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Self-assembly of high-dimensional architecture from Strandberg-type polyoxometalate clusters and silver ions

✍ Scribed by Chun-Xia Zhang; Ya-Guang Chen; Qun Tang; Zhi-Chao Zhang; Dan-Dan Liu; Hua-Xin Meng


Book ID
113662025
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
617 KB
Volume
17
Category
Article
ISSN
1387-7003

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip