Self-assembly of dinuclear helical and non-helical complexes with copper(I)
✍ Scribed by Ruettimann, Stephane; Piguet, Claude; Bernardinelli, Gerald; Bocquet, Bernard; Williams, Alan F.
- Book ID
- 121265148
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 995 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
## Abstract Review: 132 refs.
## Abstract The copper(II) complexes [Cu(H~2~L^1^)Cl~2~]~2~[CuCl~4~]·CH~3~CN·H~2~O (HL^1^ = __N__‐6‐(4‐hydroxyphenyl)‐2‐pyridylmethyl‐__N__,__N′__,__N′__‐trimethylethylenediamine), [Cu(HL^2^)Cl~2~] (HL^2^ = __N__‐4‐hydroxybenzylmethyl‐__N__,__N′__,__N′__‐trimethylethylenediamine)and [Cu~2~(μ‐L^3^)~
## Abstract The polycondensation of a dihydrazino‐pyrimidine (**5** and **6**) with a pyrimidine‐dicarbaldehyde (**7** and **8b**) provides an efficent access to helical polymeric strands based on the formation of hydrazone connections between the pyrimidine groups. The folding into a helical struc