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Self-Assembly of Chiral Coordination Polymers and Macrocycles: A Metal Template Effect on the Polymer−Macrocycle Equilibrium

✍ Scribed by Burchell, Tara J.; Puddephatt, Richard J.

Book ID
120329481
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
911 KB
Volume
44
Category
Article
ISSN
0020-1669

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✍ Dieter Fenske; Alexander Rothenberger; Maryam Shafaei Fallah 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 151 KB

## Abstract The cluster chemistry with functionalised trimethylsilyl reagents was investigated. The oxidation of the one‐dimensional coordination polymer 1/~∞~[{Ag~2~(PhS~2~P−PS~2~Ph)dppe}·dppe]~∞~ leads to the formation of [Ag~12~(PhS~2~P−PS~2~Ph)~6~(dppeS)~6~] (dppeS = Ph~2~P(CH~2~)~2~P(S)Ph~2~].