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Self-assembly of calix[4]arene amine derivatives

✍ Scribed by O'Toole, Laura; McGinley, John; Creaven, Bernadette S.

Book ID
120552801
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
974 KB
Volume
69
Category
Article
ISSN
0040-4020

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## Abstract In solvents such as chloroform or benzene, tetraurea calix[4]arenes **1** form dimeric capsules in which one solvent molecule is usually included as guest. To explore the structural requirements for the formation of such hydrogen‐bonded dimers we replaced one __p__‐tolylurea residue by

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Two [2] catenanes, in which one calix [4]arene subunit is incorporated into the tetracationic ring, have been synthesized, the calix[4]arene moieties influence remarkably the conformation and solubility of the resulting catenanes.