✦ LIBER ✦

Self-assembly of aniline oligomers and their induced polyaniline supra-molecular structures

✍ Scribed by Feng, Jing; Jing, Xinli; Li, Yu

Book ID: 120305532
Publisher: Versita
Year: 2013
Tongue: English
Weight: 720 KB
Volume: 67
Category: Article
ISSN: 0366-6352
DOI: 10.2478/s11696-013-0376-y

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Aniline chemical oxidative polymerisation (COP), which produces various polyaniline (PANI) and oligoaniline supra-molecular structures, can be regarded as an in situ self-assembly process. This review provides a brief introduction to recent work on the structural characters and self-assembly behaviours of oligomeric aniline chemical oxidation products; it is focused on the relationships between the oligomeric species and morphology of the final products such as PANI nanoparticles, nanofibres/rods, nanotubes or oligoaniline nanosheets, micro/nanospheres in aniline COP systems. Several mechanisms proposed as explanations for the formation of typical supra-molecular structures are discussed in order to illustrate the roles of aniline oligomers. This article concludes with our perspectives on future work remaining to be done to uncover the formation mechanism of supra-molecular structures constructed by aniline chemical oxidation products and their controllable synthesis.

📜 SIMILAR VOLUMES

Formation of o-Phenylenediamine Oligomer

Formation of o-Phenylenediamine Oligomers and their Self-Assembly into One-Dimensional Structures in Aqueous Medium

✍ Xuping Sun; Shaojun Dong; Erkang Wang 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB

## Abstract **Summary:** Uniform one‐dimensional (1D) structures of __o__‐phenylenediamine (oPD) oligomers are obtained by direct mix of AgNO~3~ and oPD aqueous solutions at room temperature. The formation of the 1D structures involves two stages: (1) oxidation of oPD by AgNO~3~, yielding individua

Molecular recognition and the design of

Molecular recognition and the design of solid state structures: protonation-induced conformational change and self-assembly of 2,6-diamidopyridinium phosphates

✍ Geib, Steven J.; Hirst, Simon C.; Vicent, Cristina; Hamilton, Andrew D. 📂 Article 📅 1991 🏛 The Royal Society of Chemistry 🌐 English ⚖ 317 KB

Influence of the Molecular Structure and

Influence of the Molecular Structure and Morphology of Self-Assembled 1,3,5-Benzenetrisamide Nanofibers on their Mechanical Properties

✍ Daniel Kluge; Julia C. Singer; Jens W. Neubauer; Frank Abraham; Hans-Werner Schm 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 764 KB

Corrigendum: Influence of the Molecular

Corrigendum: Influence of the Molecular Structure and Morphology of Self-Assembled 1,3,5-Benzenetrisamide Nanofibers on their Mechanical Properties

✍ Kluge, Daniel; Singer, Julia C.; Neubauer, Jens W.; Abraham, Frank; Schmidt, Han 📂 Article 📅 2013 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

Use of Specific Functionalised Tips with

Use of Specific Functionalised Tips with STM: A New Identification Method of Ester Groups and Their Molecular Structure in Self-Assembled Overlayers

✍ Cedric Volcke; Priscilla Simonis; François Durant; Paul A. Thiry; Philippe Lambi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB

Single Component Self-Assembled Monolaye

Single Component Self-Assembled Monolayers of Aromatic Azo-Biphenyl: Influence of the Packing Tightness on the SAM Structure and Light-Induced Molecular Movements

✍ Mark Elbing; Alfred Błaszczyk; Carsten von Hänisch; Marcel Mayor; Violetta Ferri 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 775 KB