Self-assembly of 1D Coordination Polymers Containing Copper(I)tert-butylthiolato Clusters: Structural Characterization and Properties
โ Scribed by Zhihua Li; Xiuling Li; Ping Lin; Shaowu Du
- Book ID
- 106406378
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 468 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1040-7278
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๐ SIMILAR VOLUMES
Two new polynuclear complexes of Cu II , [Cu 2 (fum)(ยต-OH)(bpy) 2 (H 2 O)](NO 3 )โข2H 2 O (1) (fum = fumarate dianion, bpy = 2,2ะ-bipyridine) and [Cu(fum)(tmen)]โข2H 2 O (2) (tmen = N,N,Nะ,Nะ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.
## Abstract Treatment of CuI with PhSCH~2~SPh in MeCN solution affords, by a selfโassembly reaction, the monodimensional metalโorganic coordination polymer [Cu~4~I~4~{ฮผโPhS~2~CH~2~SPh}~2~]__~n~__ (1), in which Cu~4~(ฮผ^3^โI)~4~ cluster units are linked by the dithioether ligand in a 1D necklace stru