Self-Assembly of 1,3,5-Benzenetricarboxylic (Trimesic) Acid and Its Analogues
β Scribed by Sergei V. Kolotuchin; Paul A. Thiessen; Edward E. Fenlon; Scott R. Wilson; Colin J. Loweth; Steven C. Zimmerman
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 327 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0947-6539
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## Abstract A series of novel triorganotin(IV) complexes of the type [(R~3~Sn)~3~(TMA)]Β·YΒ·L [R = CH~3~, Y = 3CH~3~OH (1); R = CH~3~, Y = 2CH~3~OH (2); R = C~6~H~5~CH~2~ (3); R = __o__βFβC~6~H~4~CH~2~ (4); R = __o__βClβC~6~H~4~CH~2~ (5); R = C~6~H~5~, L = CH~2~Cl~2~ (6); R = C~6~H~5~, L = EtOHΒ·2H~2~
Dinitrobenzoic acid, 1, forms a 2:1 molecular complex with 1,4-diiodobenzene, 2, through the formation of iodo-nitro interactions utilising one of its nitro groups, rather than forming a 1 : 1 molecular complex using both the nitro groups. The result suggests the importance of the hydrogen bond inte