Self-Assembly Molecular Squares with Metal Complexes as Bridging Ligands
β Scribed by Sun, Shih-Sheng; Silva, Alexsandra S.; Brinn, Ira M.; Lees, Alistair J.
- Book ID
- 120382827
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 50 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
A series of novel heterometallic square complexes with the general molecular formulas {fac-Br(CO) 3 Re [Β΅-(pyterpy) 2 M]} 4 (PF 6 ) 8 and {(dppf)Pd [Β΅-(pyterpy) 2 Ru]} 4 (PF 6 ) 8 (OTf 8 (4), where M ) Fe (1), Ru (2), or Os (3), pyterpy is 4β²-(4β²β²β²-pyridyl)-2,2β²:6β²,2β²β²-terpyridine, dppf ) 1,1β²-bis(d
## Abstract A bridged silsesquioxane was obtained from a precursor synthesized by the reaction of glycidoxypropyl(trimethoxysilane) (2 mol) with cyclohexylamine (1 mol). The polycondensation in the presence of formic acid produced a hybrid material exhibiting a shortβrange order based on elongated