## Abstract Novel fullerene‐grafted poly(3‐hexylthiophene) (P3HT)‐based rod‐coil block copolymers have been synthesized. The regioregular P3HT rod block has been synthesized by a modified Grignard metathesis reaction (GRIM). An original in situ end‐capping reaction has been developed in order to co
✦ LIBER ✦
Self-Assembling of Novel Fullerene-Grafted Donor–Acceptor Rod−Coil Block Copolymers
✍ Scribed by Barrau, Sophie; Heiser, Thomas; Richard, Fanny; Brochon, Cyril; Ngov, Chheng; van de Wetering, Karin; Hadziioannou, Georges; Anokhin, Denis V.; Ivanov, Dimitri A.
- Book ID
- 126037363
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 776 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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**Organized structures over length scales differing by 10^3^** are reported, i.e., crystals of rod block (unit cell ∼ 1 nm), block copolymer microdomains (layer periodicity ∼ 50 nm), and Néel domain walls (wall periodicity ∼ 1000 nm)—see Figure and inside front cover. The result is an example of com
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