Self-assembled structures and chemical reactions in room-temperature ionic liquids
β Scribed by Jingcheng Hao; Thomas Zemb
- Book ID
- 104014107
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 940 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1359-0294
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β¦ Synopsis
Amphiphilic association in room-temperature ionic liquids (RT-ILs)a "green" solvent shows analogies as well as clear differences from self-assembly in water. In this review, we summarize the known features of amphiphilic association structures in the form of micelles, microemulsions, vesicles and lyotropic liquid-crystalline phases in ionic liquids. Most of the methods making use of association to control reactivity could be developed also in RT-ILs and we give a few recently published examples of this strategy.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
The Diels-Alder cycloaddifion reaction between methyl acrylate and cyclo~tadiene has been investigated in a number of air and moisture stable ionic liquids. The endo/exo ratio of the reaction has been used as an initial probe of the nature of the solvents.