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Selenoxides Are Better Hydrogen-Bond Acceptors than Sulfoxides: a Crystallographic Database and Theoretical Investigation

โœ Scribed by Renault, Eric; Le Questel, Jean-Yves


Book ID
126022540
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
291 KB
Volume
108
Category
Article
ISSN
1089-5639

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The hydrogen-bond ability of nitrogen in X-CNรรรHO-R systems was investigated using crystallographic data retrieved from the Cambridge Structural Database and via ab initio calculations. The classification of hydrogen-bond geometries by the nature of the donor shows that the strength of the interact