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Selenium-Catalyzed Reductive Carbonylation of 2-Nitrophenols to 2-Benzoxazolones.

โœ Scribed by Xiaofang Wang; Gang Ling; Yan Xue; Shiwei Lu


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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Selenium-Catalyzed Reductive Carbonylati
โœ Xiaofang Wang; Gang Ling; Yan Xue; Shiwei Lu ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 93 KB

## Abstract 2โ€Benzoxazolones or 2โ€benzimidazolones are synthesized in moderate to good yields in the presence of a base (KOH, NaOH, KOAc, NEt~3~, DBU) at atmospheric pressure or under a high pressure of CO by oneโ€pot reductive carbonylation of 2โ€nitrophenols or 2โ€nitroaniline in the presence of sel