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Selenium catalyzed generation of diimide from hydrazine. Selenium as a novel oxidizing reagent

✍ Scribed by Kiyoshi Kondo; Shinji Murai; Noboru Sonoda

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 216 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83337-2

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✦ Synopsis

Since the work of van Tamelen and Corey in 1961, diimide' has been used successfully as a reducing agent for stereospecific cis-hydrogenation of multiple bonds of olefins, acetylenes, and azo compounds. The stereospecificity has been interpreted in terms of a cyclic transition stateL, which

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