Selenation/Thionation of α-Amino Acids: Formation and X-ray Structures of Diselenopiperazine and Dithiopiperazine and Related Compounds
✍ Scribed by Guoxiong Hua; Amy L. Fuller; Michael Bühl; Alexandra M. Z. Slawin; J. Derek Woollins
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 436 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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A series of germasesquioxides and germatranes containing ␣-amino acid or ␣-aminophosphonic acid moieties was synthesized by the reaction of b-trichlorogermylpropionyl chloride with ␣-amino acid esters or ␣-aminophosphonates. The structures of all products were confirmed by 1 H NMR, 31 P NMR, and IR
## Abstract X‐ray structural data for α‐aminopropanephosphonic acid (APPA), together with ^1^H NMR spectroscopy including PANIC and WIN‐DAISY spectral simulation, and theoretical calculations using the programs VAMP 4.4 (PM3) and GAUSSIAN 92 (3–21G\*\*), confirm an antistaggered relationship betwee