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Selectivity of the reaction of free radicals with styrene

โœ Scribed by Moad, Graeme; Rizzardo, Ezio; Solomon, David H.

Book ID
120347147
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
831 KB
Volume
15
Category
Article
ISSN
0024-9297

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Initiation mechanisms in free radical polymerization: Competitive reaction of cyanoisopropyl radicals with styrene and acrylonitrile
โœ W. Ken Busfield; Ian D. Jenkins; Phuc Van Le ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 147 KB ๐Ÿ‘ 3 views

The competitive reactions of cyanoisopropyl radicals with the mixed monomers styrene and acrylonitrile have been investigated using the nitroxide radical trapping technique. When the trap concentration is kept low, second, third, and even fourth generation (in terms of successive monomer addition) c