Selectivity of a Resorcinarene Host for Pentanol Isomers
✍ Scribed by Caira, Mino R.; le Roex, Tanya; Nassimbeni, Luigi R.
- Book ID
- 121349282
- Publisher
- Taylor and Francis Group
- Year
- 2004
- Tongue
- English
- Weight
- 445 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1061-0278
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## Abstract Phosphonium salt host compounds **1**–**3** form inclusion crystals with cyclohexane‐1,3‐diol (**4**), cyclohexane‐1,4‐diol (**5**) and cyclohexane‐1,3,5‐triol (**6**), in which the equatorial conformers are selectively included. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germ
We propose a new fullerene growth model with a novel picture for selective isomer formation of higher fullerenes. The model described supposes that the fullerene intermediates, consisting of a 5-and &membered ring network (a cap-like structure), undergo a facile interconversion by a "pentagon migrat