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Selectivity in radical cation Diels-Alder reactions of indole and electron-rich dienes - a semiempirical approach

โœ Scribed by Wiest, Olaf; Steckhan, Eberhard; Grein, Fritz


Book ID
120485905
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
509 KB
Volume
57
Category
Article
ISSN
0022-3263

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## Abstract The reactivity and selectivity of the the captodative olefins 1โ€acylvinyl benzoates **1a**โ€“**1f** and **3a** as heterodienes in hetero__โ€Diels__โ€“__Alder__ reactions in the presence of electronโ€rich dienophiles is described. Heterodienes **1** undergo regioselective cycloaddition with th