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Selective transformations of alkynols catalyzed by ruthenium complexes

✍ Scribed by Christian Bruneau; Zahia Kabouche; Muriel Neveux; Bénédicte Seiller; Pierre H. Dixneuf


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
964 KB
Volume
222
Category
Article
ISSN
0020-1693

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Selective oxidation of cyclohexene catal
✍ Ziqiang Lei 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 105 KB

Cyclohexene was oxidized to 2-cyclohexen-1-ol and 2-cyclohexen-1-one by atmospheric pressure of molecular oxygen in the presence of linear polystyrene-bound-2,29-bipyridine-ruthenium complexes in the absence of solvent at 70658C selectively. The alcohol / ketone molar ratio of the products can be ad