𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Selective Synthesis of Substituted Pyrrole-2-phosphine Oxides and -phosphonates from 2 H -Azirines and Enolates from Acetyl Acetates and Malonates

✍ Scribed by Palacios, Francisco; Ochoa de Retana, Ana M.; Vélez del Burgo, Ander

Book ID
121475181
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
855 KB
Volume
76
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Easy and efficient synthesis of enantiom
Easy and efficient synthesis of enantiomerically enriched 2H-azirines derived from phosphonates
✍ Francisco Palacios; Ana M Ochoa de Retana; José I Gil 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 156 KB

An ecient synthesis of 2H-azirines substituted with a phosphonate group is described. The key step is an alkaloid-mediated Neber reaction of b-ketoxime tosylates. Reduction of 2H-azirines with sodium borohydride in ethanol gives 2-phosphorylated cis-aziridines.