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Selective synthesis of novel 2-imino-1,3-selenazolidin-4-ones and 2-amino-1,3,4-selenadiazin-5-ones from isoselenocyanates

✍ Scribed by Yuanyuan Xie; Junli Liu; Jianjun Li

Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 518 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.12.068

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✦ Synopsis

An efficient and regioselective synthesis of 2-imino-1,3-selenazolidin-4-ones and 2-amino-1,3,4-selenadiazin-5-ones was achieved via one-pot reaction of isoselenocyanates, hydrazines, and ethyl chloroacetate or chloroacetyl chloride, respectively. Plausible mechanisms for these transformations were given.

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