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Selective synthesis of (E)-crotylsilanes by reaction of crotylmagnesium bromide with hydrosilanes in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II)

✍ Scribed by Tamio Hayashi; Keiji Kabeta; Makoto Kumada


Book ID
104232643
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
137 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Dichloro[l,l'-bis(diphenylphosphino)ferrocene]nickel(II) was found to be an effective catalyst for the reaction of crotylmagnesium bromide with hydrosilanes to give (E)-crotylsilanes selectively.