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Selective Synthesis of 2-Pyridones and Pyrimidine-2,4-diones by Neutral Rhodium(I) Complex-Catalyzed Cyclocotrimerization of Alkenes and Isocyanates.

โœ Scribed by Teruyuki Kondo; Masato Nomura; Yasuyuki Ura; Kenji Wada; Take-aki Mitsudo


Book ID
101994808
Publisher
John Wiley and Sons
Year
2007
Weight
24 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract 1โ€Phenylpentaneโ€1, 4โ€diones, and (E)โ€5โ€hydroxyโ€5โ€phenylpentโ€3โ€enโ€2โ€ones were synthesized via organophosphineโ€catalyzed addition reaction of butโ€3โ€enโ€2โ€one with aldehydes. The features of the present protocols include high selectivity, operational simplicity, atom economy, and mild react