Selective reduction of 4h-1,3-thiazine-4-ones : Easy access to substituted 6h-1,3-thiazines
✍ Scribed by Abdesselam Abouelfida; Jean-Paul Pradère; Jean-Claude Rozé; Michel Jubault
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 122 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Selective reduction of 4H-1,3-thiazine-4-ones leads to new substituted 6H-1,3thiazines.
📜 SIMILAR VOLUMES
II2 Y s HN 4 R5 4 4 2709 1 second wave ('&I 1 EX (V.vs.SCE) -0.67(') -0.67(\*) -0.72 -0.48 -1.05 -0.52 -1.15 -0.79 (.I Splitting 1n tY0 aama1ectronic r.ve. for Cm, 5.10-3 1.
4H-1,3-thiazines or their mixtures with 5-alkylidene-4H-5, 6-dihydro-l,3 -thiazines were obtained by cyclization of methyl N-3-oxoaKytdithiocarbamates in sulfuric acid. The regiospecificity of the reaction is determined by the structures of the starting compounds. The structures of the synthesized