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Selective reactions between phenols and formaldehyde. A novel route to salicylaldehydes

โœ Scribed by Casiraghi, Giovanni; Casnati, Giuseppe; Puglia, Giuseppe; Sartori, Giovanni; Terenghi, Giuliana

Book ID
111910566
Publisher
Royal Society of Chemistry
Year
1980
Weight
543 KB
Volume
0
Category
Article
ISSN
1472-7781

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The acetoxymethyl rhodium compounds [(ฮท 5 -the formaldehyde compounds [(ฮท 5 -C 5 R 5 )Rh(ฮท 2 -CH 2 O)(L)] (24-27). The related thioformaldehyde complexes [(ฮท 5 -C 5 R 5 )Rh(CH 2 OAc)(L)I] (4, 13-16) which were prepared from the chloromethyl derivatives [(ฮท 5 -C 5 R 5 )Rh(CH 2 Cl)(L)I] and C 5 Me 5 )