✦ LIBER ✦

Selective radical synthesis of β-C-disaccharides

✍ Scribed by Boris Vauzeilles; Pierre Sinaÿ

Book ID: 104231582
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 91 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01533-7

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✦ Synopsis

Several b-C-disaccharides have been selectively synthesized by radical cyclization of two temporarily tethered functionalized monosaccharides. In this process, intramolecular addition of a carbohydrate-derived radical onto an anomeric exomethylene group, followed by axial hydrogen addition, resulted in b stereochemistry.

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