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Selective proton ⇌ deuterium substitution for probing molecular structure by NMR relaxation analysis

✍ Scribed by Nadia Marchettini; Alessandro Donati; Claudio Rossi


Book ID
103030476
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
290 KB
Volume
180
Category
Article
ISSN
0009-2614

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✦ Synopsis


The effects on proton NMR relaxation parameters are analysed in relation to the proton-deuterium selective isotopic substitution. A method for the calculation of the direct relaxation contribu:ion between structural protons (protons not involved in the HtiD exchange) and mobile nuclei is developed. The proposed experiment is applied for studying the structural properties of kinetine riboside.