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Selective preparation of optically pure (R,R)-1,1′:5′,1″-ternaphthalene-2,2′,6′,2″-tetraol: A new higher homolog of BINOL

✍ Scribed by Takashi Sugimura; Shintaro Inoue; Akira Tai

Book ID: 104259760
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 205 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01381-1

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✦ Synopsis

As a new chiral auxiliary, the title compound of an enantiomerically pure higher homolog of BINOL was synthesized through stepwise formation of optically pure 2,4-pentanediol tethers connecting three naphthyl groups by Mitsunobu reaction, oxidative intramolecular coupling, and elimination of the tethers.

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