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Selective Oxidation of Arylaldoximes by Cetyltrimethylammonium Dichromate to Arylaldehydes and Arylnitriles.

โœ Scribed by Sandhyamayee Sahu; Sabita Patel; Bijay K. Mishra

Publisher
John Wiley and Sons
Year
2006
Weight
20 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis of cetyltrimethylammonium trib
Synthesis of cetyltrimethylammonium tribromide (CTMATB) and its application in the selective oxidation of sulfides to sulfoxides
โœ Gopa Kar; Anil K. Saikia; Upasana Bora; Sanjoy K. Dehury; Mihir K. Chaudhuri ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 189 KB

The bright yellow crystalline cetyltrimethylammonium tribromide (CTMATB) reagent has been synthesized from the reaction of CTMAB and KBr with H 2 MoO 4 โ€ขH 2 O, H 2 O 2 and H 2 SO 4 in the molar ratio 1:2:0.01:4:0.93. CTMATB selectively oxidizes a variety of dialkyl and alkyl aryl sulfides to the cor