Selective oxidation of alcohols with oxygen on Ru–Co-hydroxyapatite: A mechanistic study
✍ Scribed by Z. Opre; J.-D. Grunwaldt; T. Mallat; A. Baiker
- Book ID
- 108211593
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 346 KB
- Volume
- 242
- Category
- Article
- ISSN
- 1381-1169
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## Abstract The heterogeneous oxidation of various alcohols with oxygen catalysed by TPAP‐doped ormosils in scCO~2~ at 75 °C and 22.0 MPa has been studied in detail. Sol‐gel segregation of TPAP into the inner porosity of an organically modified silica (ormosil) xerogel along with the use of a react
## Abstract Oxidation of sulfides with PhIO/RuCl~2~ (PPh~3~)~3~ leads to sulfones. Electronwithdrawing substituents in the aromatic ring of PhIO reduce the reactivity and improves selectivity of the system. Thus, with __m__‐iodosylbenzoic acid sulfides are converted to sulfoxide. Under the same con