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Selective oxidation of alcohols with hydrogen peroxide catalyzed by hexadentate binding 8-quinolinolato manganese(III) complexes

✍ Scribed by Zhengpei Ye; Zaihui Fu; Sheng Zhong; Fang Xie; Xiaoping Zhou; Fenglan Liu; Dulin Yin


Book ID
113686567
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
304 KB
Volume
261
Category
Article
ISSN
0021-9517

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Oxidation of (+)-3-carene (1), nerol (2) and geraniol (3) by hydrogen peroxide in the presence of catalytic amounts of several manganese(III) porphyrin complexes with electron withdrawing and electron donating groups was examined. The reactions were carried out at room temperature in acetonitrile, u