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Selective oxidation of alcohols with hexadecyl silica supported cupric nitrate

โœ Scribed by Farajollah Mohanazadeh; Shohreh Ghamsari

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
234 KB
Volume
29
Category
Article
ISSN
1381-5148

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โœฆ Synopsis

Preparation of hexadecyl silica supported cupric nitrate is described. This oxidant, in carbon tetrachloride, oxidizes alcohols to their corresponding carbonyl compounds. It oxidizes primary alcohols in the presence of secondary alcohols with absolute chemoselectivity in high yields.

๐Ÿ“œ SIMILAR VOLUMES

Oxidation of alcohols by metal nitrates
Oxidation of alcohols by metal nitrates supported on silica gel
โœ Takeshi Nishiguchi; Fumi Asano ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 117 KB

Many metal nitrates, especially zinc(I1) and copper(I1) nitrates, supported on silica gel, oxidized secondary and benzylic alcohols to the corresponding ketones and aldehydes efficiently. The supported reagent technique has received increasing attention in recent years.l As one oxidizng reagent of a