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selective methyl formate homologation into methyl acetate catalyzed by rhodium complexes

✍ Scribed by Serge Melloul; Bruno Seuillet; Yves Castanet; André Mortreux; Francis Petit

Publisher
Elsevier Science
Year
1990
Weight
431 KB
Volume
60
Category
Article
ISSN
0304-5102

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📜 SIMILAR VOLUMES

On the rhodium catalyzed formation of ac
On the rhodium catalyzed formation of acetic acid from methyl formate — comparison with the rhodium catalyzed formation of acetic acid by direct carbonylation of methanol
✍ G. Bub; H.-U. Hög 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 662 KB

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.