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Selective Metal-Halogen Exchange of 4,4′-Dibromobiphenyl Mediated by Lithium Tributylmagnesiate.

✍ Scribed by Sarah J. Dolman; Francis Gosselin; Paul D. O'Shea; Ian W. Davies


Book ID
101994594
Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Selective Halogen-L
✍ M. LARSEN; M. JOERGENSEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Selective Halogen-Lithium Exchange Reaction of Bromine-Substituted 25, 26,27,28-Tetrapropoxycalix(4)arene (Ia). -The selective bromine-lithium exchange of (Ia) with either BuLi or tBuLi in THF followed by quenching of the lithiated derivatives with MeOH, D2O, Me2S2, B(OMe)3, DMF, or CO2 as electrop