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Selective isomerization of aryl substituted epoxides to aldehydes via iron Lewis acid catalysis

โœ Scribed by John Picione; Syed J. Mahmood; Andy Gill; Marion Hilliard; M.Mahmun Hossain


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
181 KB
Volume
39
Category
Article
ISSN
0040-4039

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Lewis acid-promoted selective rearrangem
โœ Keiji Maruoka; Noriaki Murase; Ronan Bureau; Takashi Ooi; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 613 KB

Rearrangement of trisubstituted epoxides has been effected under the influence of various Lewis acids. Among these, methylaluminum bis(4-bromo-2,6-di-t-butylphenoxide) (MABR) can be selectively rearranged from trisubstituted epoxides to aldehydes, while antimony pentafluoride is employable for selec