All the geometric isomers of the benzoate derivatives, XC 6 H 4 CO 2 À (X ¼ F, Cl, Br, OH, OCH 3 , NO 2 , CO 2 CH 3 , NH 2 , N(CH 3 ) 2 ) can be intercalated into the layered double hydroxide [LiAl 2 (OH) 6 ]Cl Á H 2 O in 50% (v/v) water/ethanol solution at 80 1C to give fully anionexchanged first s
Selective Ion-Exchange Intercalation of Isomeric Dicarboxylate Anions into the Layered Double Hydroxide [LiAl 2 (OH) 6 ]Cl·H 2 O
✍ Scribed by Fogg, Andrew M.; Dunn, Jenifer S.; Shyu, Shin-Guang; Cary, Douglas R.; O'Hare, Dermot
- Book ID
- 120238139
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 119 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0897-4756
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Quantitative investigation of the shape selectivity for the competitive intercalation reaction of isomeric mixtures in the interlayer of LDH was achieved by analyzing the solid phases synthesized by the reaction of [LiAl(2)(OH)(6)]Cl.yH(2)O with various compositional mixtures of (E,E)- and (Z,Z)-muc
A series of layered double hydroxide materials of composition Co 2 Fe y Al 1Ày (OH) 6 Cl . nH 2 O (0ryr1) was prepared via chimie douce. The crystalline parameter related to the cation to cation distance obeys the expected variation, showing that the substitution is effective over the entire range.