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Selective hydrogenation of polynitroaromatic derivatives with noble metal catalysts in the presence of catalytic amounts of iron

โœ Scribed by George Theodoridis; Mark C Manfredi; Jessica D Krebs

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
248 KB
Volume
31
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Hydrogen over PtOs, 5%Pd(c), PdCts, or S%Rh(AI .$&), in the presence of catalytic amounts of iron and under mild reaction conditions, resulted in the selective reduction of a variety of polynitroaromatic compounds in high yields.

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Zerovalent palladium, platinum and rhodium catalysts dispersed in thin poly(pyrrole-alkylammonium) films coated on carbon electrodes have been applied to the electrocatalytic hydrogenation of organic substates containing two different carbon-carbon double bonds, namely limonene and carvone. Results