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Selective hydrogenation of citral over gold nanoparticles on alumina

✍ Scribed by C. Caballero; J. Valencia; M. Barrera; A. Gil


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
624 KB
Volume
203
Category
Article
ISSN
0032-5910

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✦ Synopsis


Gold nanoparticles have been supported on alumina by wet impregnation in the presence of sodium citrate and polyvinyl alcohol. The catalytic performance of these catalysts for the selective hydrogenation of 3,7dimethyl-2,6-octadienal (citral) in the liquid phase has been evaluated. The presence of polyvinyl alcohol significantly improved the selectivity to cis-3,7-dimethyl-2,6-octadien-1-ol (nerol).


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## Abstract **BACKGROUND:** Well‐dispersed nanoparticles of palladium were synthesized by wet impregnation technique over bentonite followed by three different reduction methods (H~2~ or NaBH~4~ or ethanol) and characterized by transmission electron microscopy, X‐ray diffraction, temperature‐progra