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Selective hydride-mediated conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds using [(Ph3P)CuH]6

โœ Scribed by Mahoney, Wayne S.; Brestensky, Donna M.; Stryker, Jeffrey M.


Book ID
120069505
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
414 KB
Volume
110
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Conjugate reduction of polyfunctional ฮฑ,
โœ Thomas M. Koenig; John F. Daeuble; Donna M. Brestensky; Jeffrey M. Stryker ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 301 KB

In contrast to organocuprate conjugate addition and standard methods for conjugate reduction, use of the stable copper0 hydride cluster, [(ph3p)cuH)6, allows chemoselective conjugate reduction of o&msaturated carbonyl compounds substituted at the ~position with leaving groups. In addition, the compa