## Abstract We present the application of a 2D broadband homodecoupled proton NMR experiment to the visualization of enantiomers. In a chiral environment, the existence of diastereoisomeric intermolecular interactions can yield—generally slight—variations of proton chemical shifts from one enantiom
✦ LIBER ✦
Selective Homonuclear Decoupling in 1 H NMR: Application to Visualization of Enantiomers in Chiral Aligning Medium and Simplified Analyses of Spectra in Isotropic Solutions
✍ Scribed by Prabhu, Uday Ramesh; Suryaprakash, N.
- Book ID
- 126763354
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 448 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Two‐dimensional ^1^H NMR experiments that achieve band‐selective, homonuclear decoupling in both the indirectly detected F1 and directly detected F2 dimensions were used to assign the highly overlapped ^1^H NMR spectrum of the peptide Ac‐SRGKARVRAKVKDQTK‐NH~2~, both free in solution and