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Selective heteronuclear chemical shift correlation without soft pulses

✍ Scribed by M. A. Delsuc; E. Guittet; J. Y. Lallemand

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 242 KB
Volume: 23
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260230317

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✦ Synopsis

Abstract

The elucidation of ^1^H‐^13^C connectivities is one of the most powerful NMR tools for the determination of unknown structures, and a new one‐dimensional correlation technique is presented, based on a modified INEPT sequence. Omission of the first two 180° refocusing pulses and randomization of the mixing delay realize addition of a ^13^C bearing the selected ^1^H. This technique avoids resorting to the acquisition time and data storage consuming two‐dimensional approaches, and does not require any selective pulse or decoupling.

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