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Selective Formation of Rhodium Diacyl or Acyl Hydrido Hemiaminal Complexes in the Reaction of o -(Diphenylphosphino)benzaldehyde with Rhodium 2-Aminopyridine or 2-(Aminomethyl)pyridine Compounds

✍ Scribed by Garralda, María A.; Hernández, Ricardo; Ibarlucea, Lourdes; Pinilla, Elena; Torres, M. Rosario; Zarandona, Malkoa

Book ID
127132181
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
173 KB
Volume
26
Category
Article
ISSN
0276-7333

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Formation of 18e− and 16e− Acyl(η3-cyclooctenyl)rhodium(III) Complexes in the Reaction of Cationic (Cycloocta-1,5-diene)rhodium(I) Compounds with 2-(Diphenylphosphino)benzaldehyde
✍ Rachad El Mail; María A. Garralda; Ricardo Hernández; Lourdes Ibarlucea; Elena P 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 137 KB 👁 1 views

The reaction of cationic diolefinic rhodium(I) complexes with 2-(diphenylphosphino)benzaldehyde (pCHO) was studied. [Rh(cod) 2 ]ClO 4 (cod cycloocta-1,5-diene) reacted with pCHO to undergo the oxidative addition of one pCHO with (1,2,3-h)cyclooct-2-en-1-yl (h 3 -C 8 H 13 ) formation, and the coordin